• Title of article

    Structure of [Ni(dippe)(μ-S)]2 and its reaction products. The nucleophilicity of the Ni2S2 fragment

  • Author/Authors

    Stephen S. Oster، نويسنده , , Rene J. Lachicotte، نويسنده , , William D. Jones، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    10
  • From page
    118
  • To page
    127
  • Abstract
    The dimer [(dippe)Ni(μ-S)]2 reacts with organic electrophiles to give the alkylated species [(dippe)2Ni2(μ-S)(μ-SR)]+. Stronger alkylating agents lead to double alkylation and cleavage of the dimer. Protonation similarly occurs with strong acids. The structures of several of these species have been determined.
  • Keywords
    nickel complexes , crystal structures , Sulfido complexes , Dinuclear complexes , Hydrodesulfurization
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2002
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321173

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321173