• Title of article

    Chelate ring-opening aminophosphine complexes of ruthenium(II)

  • Author/Authors

    Robert Morris، نويسنده , , Abraha Habtemariam، نويسنده , , Zijian Guo، نويسنده , , Peter McBurney and Simon Parsons ، نويسنده , , Peter J. Sadler، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    9
  • From page
    551
  • To page
    559
  • Abstract
    The preparations and X-ray crystal structures of the Ru(II) aminophosphine complexes trans, cis-[RuCl2(H(Bz)NCH2CH2PPh2-N,P)2] (1), trans, cis-[RuCl2(H2NCH2CH2PPh2-N,P)2] (3) and [(η6-C6H6)Ru(PPh2CH2CH2NMe2-N,P)Cl][PF6] (5) are described. Complexes 1 and 3 are octahedral and contain a marked distortion of the ClRuCl axis from linearity. Complex 3 undergoes facile chelate ring-opening in DMSO and CH3CN solutions to give complexes containing one chelated aminophosphine ligand and one pendant ligand coordinated only through P. The X-ray structure of trans, cis-[RuCl2(DMSO-S)2(H2NCH2CH2P(O)Ph2-N,O)] (4) containing an oxidised aminophosphine ligand is also reported.
  • Keywords
    Aminophosphine ligands , Chelate ring-opening , X-Ray structures , Ruthenium(II)
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2002
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321538

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321538