Title of article
Ureato(1−) complexes of palladium(II) and platinum(II): Crystal structure of [NBu4][(C6F5)2Pt{PhNC(O)NPri 2}]
Author/Authors
José Ruiz، نويسنده , , Venancio Rodr??guez، نويسنده , , Consuelo Vicente، نويسنده , , José Pérez، نويسنده , , Gregorio L?pez، نويسنده , , Penny A Chaloner، نويسنده , , Peter B Hitchcock، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
5
From page
114
To page
118
Abstract
The reaction of [NBu4]2[{M(C6F5)2(μ-OH)}2] (M=Pd, Pt) with amines R2NH in the presence of the heterocumulene phenylisocyanate, PhNCO, leads to the synthesis of the ureato(1−) complexes [NBu4][M(C6F5)2{PhNC(O)NR2}] (M=Pd, Pt). The single-crystal structure of [NBu4][(C6F5)2Pt{PhNC(O)NPri 2}] revealed the presence of a N,N′-chelating ureato(1−) with a N(1)PtN(2) bite angle of 64.0(3)°.
Keywords
palladium complexes , Ureato complexes , Phenylisocyanate , crystal structures , Platinum complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2003
Journal title
INORGANICA CHIMICA ACTA
Record number
1321684
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