Title of article
31P Chemical shift anisotropies of dihalobis(trialkylphosphine)nickel(II) complexes
Author/Authors
Dharamdat Christendat، نويسنده , , Ian.S. Butler، نويسنده , , Denis F.R. Gilson، نويسنده , , Rosemary Hynes، نويسنده , , Frederick G. Morin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
3775
To page
3779
Abstract
The 31P CP-MAS NMR spectra of trans-square-planar complexes of dihalonickel(II) complexes with tribenzyl-, tricyclohexyl- and tricyclohexylmethylphosphines have been examined and the chemical shift tensors determined. The spans, δ11–δ33, of the tensor components decrease with change in the halide, Cl > Br > I, for all the tertiary phosphines due principally to the deshielding of the δ33 component.
Keywords
nickel , Phosphine complexes , Chemical shift anisotropy
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2004
Journal title
INORGANICA CHIMICA ACTA
Record number
1322359
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