• Title of article

    Is o-carborane photoluminescent?

  • Author/Authors

    Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    3
  • From page
    4607
  • To page
    4609
  • Abstract
    At 77 K in the solid state and in ethanol glasses, o-carborane (1,2-C2B10H12) shows a relatively intense (ϕ ∼ 10−3 at λexc = 260 nm) structured photoluminescence (λmax = 441 nm).In agreement with the rather slow decay of this emission (τ ∼ 4 s) it is suggested to be a phosphorescence. While it appears to be a genuine property of o-carborane an unknown impurity as origin of this luminescence is not completely excluded.
  • Keywords
    Photoluminescence , Boron , Carboranes , Electronic spectra
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2004
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1322464