Title of article
New oligo-/poly-meric forms for MX:dpex (1:1) complexes (M = CuI, AgI; X = (pseudo-)halide; dpex = Ph2E(CH2)xEPh2, E = (P), As; x = 1, 2)
Author/Authors
Augusto Cingolani، نويسنده , , Corrado Di Nicola، نويسنده , , Effendy، نويسنده , , Claudio Pettinari، نويسنده , , Brian W. Skelton، نويسنده , , Neil Somers، نويسنده , , Allan H. White، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
15
From page
748
To page
762
Abstract
Syntheses, spectroscopic (IR, NMR and ESI MS) and single crystal X-ray structural characterizations are reported for a wide variety of adducts of Ag(oxyanion):dpem(:S) (1:1(:n))2 (oxyanion = ClO4, F3CCO2 (tfa) F3CSO3 (tfs); dpem = Ph2E(CH2)EPh2) stoichiometry among which the basic Ag(Ph2E(CH2)EPh2)2Ag core is diversely perturbed by interactions with anions and solvent molecules. ESI MS and 31P NMR spectroscopy indicated that dinuclear species also exist in solution.
Keywords
ESI MS , Silver , Diphosphine , X-ray crystal structure , 31P NMR
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2005
Journal title
INORGANICA CHIMICA ACTA
Record number
1322664
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