Title of article
The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
Author/Authors
Gulaim A. Seisenbaeva، نويسنده , , Suresh Gohil، نويسنده , , Evgeniya V. Suslova، نويسنده , , Tatiana V. Rogova، نويسنده , , Nataliya Ya. Turova، نويسنده , , Vadim G. Kessler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
7
From page
3506
To page
3512
Abstract
Interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)13, and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)12X and Fe5O(OEt)11X2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)13 isolated with higher yields.
Keywords
Iron oxo-ethoxide , Mass-spectrometry , X-ray study , Sol–gel
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2005
Journal title
INORGANICA CHIMICA ACTA
Record number
1323048
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