Title of article
Synthesis and characterization of ruthenium(II) complexes with dendritic N-heterocyclic carbene ligands
Author/Authors
Fujihara، نويسنده , , Tetsuaki and Nishida، نويسنده , , Takeru and Terao، نويسنده , , Jun and Tsuji، نويسنده , , Yasushi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
5
From page
174
To page
178
Abstract
Ru(II) complexes with a N-heterocyclic carbene ligand bearing flexible zeroth-, first-, or second-generation dendritic moieties were synthesized and characterized. The structure of the ruthenium complex with the zeroth-generation dendritic moieties was determined by X-ray crystallography. ONIOM calculations showed that the second generation dendritic moieties surrounded the ruthenium core. These complexes worked as active catalysts for the ring-closing metathesis at 25 °C.
Keywords
dendrimer , N-heterocyclic carbene , Ruthenium , ring-closing metathesis
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2014
Journal title
INORGANICA CHIMICA ACTA
Record number
1323620
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