Title of article
Synthesis, structure and electrochemistry of (ferrocene-2-propenoato-O,O′)bis[1,2-bis(diphenylphosphino)ethane-P,P′]ruthenium(II) hexafluorophosphate
Author/Authors
Ian W. Wyman، نويسنده , , Katherine N. Robertson، نويسنده , , T. Stanley Cameron، نويسنده , , Jannie C. Swarts، نويسنده , , Manuel A.S. Aquino، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
3092
To page
3096
Abstract
The complex [Ru(η2-fcpe)(dppe)2](PF6) (1), where fcpe = ferrocene-2-propenoate and dppe = 1,2-bis(diphenylphosphino)ethane, was synthesized via a “dimer disassembly” method and characterized using elemental analysis, IR spectroscopy, 1H and 31P NMR and X-ray crystallography. The redox potentials of the metal centers were assessed using cyclic voltammetry and Osteryoung square-wave voltammetry. No significant metal–metal interactions were found.
Keywords
Ferrocenecarboxylate , Ruthenium(II) , Cyclic voltammetry , Osteryoung square-wave voltammetry , X-ray structure , Metal–organometallic systems
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324088
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