Title of article
X-ray and 57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione
Author/Authors
Anife Ahmedova، نويسنده , , Ventzislav Rusanov، نويسنده , , Alan Hazell، نويسنده , , Juliusz A. Wolny، نويسنده , , Georgi Gochev، نويسنده , , Alfred X. Trautwein، نويسنده , , Mariana Mitewa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
3123
To page
3128
Abstract
Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin–spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered.
Keywords
Iron(III) complex , Cyclic triketone , M?ssbauer spectroscopy , X-ray crystal structure
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324095
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