Title of article
The formation of disulfides by the [Fe(nta)Cl2]2− catalyzed air oxidation of thiols and dithiols
Author/Authors
Marc A. Walters، نويسنده , , Jacqueline Chaparro، نويسنده , , Talha Siddiqui، نويسنده , , Florence Williams، نويسنده , , Caleb Ulku، نويسنده , , Arnold L. Rheingold، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
3996
To page
4000
Abstract
The complexes (cnt)2[Fe(nta)Cl2], where nta = nitrilotriacetate and cnt = Et4N+ or PyH+, catalyze the air oxidation of thiols to disulfides under ambient conditions. Dithiols are converted to linear and cyclic oligomers that differ in their terminal groups as a function of the counterion, cnt. Cysteine ethyl ester was converted to the corresponding cystine diethylester in high yield.
Keywords
Thiol , Disulfides , Catalysis , Iron , Nitrilotriacetate
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324208
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