Title of article
Further kinetics studies of intermediates formed by flash photolysis of Mo(CO)6
Author/Authors
Diz، نويسنده , , Enrique Lozano and Ford، نويسنده , , Peter C.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
5
From page
3084
To page
3088
Abstract
Kinetics studies of the behavior of Mo(CO)5(CH) in the presence of radical initiators were conducted in cyclohexane (CH) solution by laser flash photolysis with time-resolved infrared detection. Activation parameters were determined for reactions of Mo(CO)5(CH) with toluene and with photochemical radical generator dibenzylketone (DBK) in the presence of excess CO.
Keywords
Molybdenum , carbonyl , TRIR , Kinetics , Mechanism
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2008
Journal title
INORGANICA CHIMICA ACTA
Record number
1326252
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