Title of article
The complexes: RhCl(P–N)(THP), where P–N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P–N][THP(O)] containing O-bonded phosphine oxides
Author/Authors
Lorenzini، نويسنده , , Fabio and Patrick، نويسنده , , Brian O. and James، نويسنده , , Brian R.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
6
From page
3199
To page
3204
Abstract
The complex RhCl(P–N)(THP) (1) is synthesized under argon from RhCl(cod)(THP) and P–N, and is structurally characterized; P–N = P,N-chelated o-diphenylphosphino-N,N-dimethylaniline, THP = tris(hydroxymethyl)phosphine, and cod = 1,5-cyclo-octadiene. The corresponding synthesis in air yields RhCl[(O)P–N][THP(O)] (2), containing O-bonded phosphine oxide ligands.
Keywords
Phosphine oxides , phosphines , Oxidation , X-ray structure , Rhodium complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2008
Journal title
INORGANICA CHIMICA ACTA
Record number
1326278
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