Title of article
Low temperature specific heat of the single molecule magnet Fe8
Author/Authors
Gomes، نويسنده , , A.M. and Novak، نويسنده , , Ma. Cristiana Nunes، نويسنده , , W.C. and Rapp، نويسنده , , R.E.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
5
From page
3975
To page
3979
Abstract
We present low temperature specific heat and ac-susceptibility measurements of Fe8 powdered sample. Below 1.3 K, super-paramagnetic blocking effects and an excess specific heat contribution are observed. The latter is attributed to a splitting of the ground state doublet in an inhomogeneous local field of hyperfine and dipolar origin. The local field contributions are evident at the resonances observed in the field dependent ac-susceptibility and specific heat below 0.5 K. The low temperature Schottky contribution is in agreement with known crystal field parameters of effective spin Hamiltonians proposed to simulate EPR and inelastic neutron scattering experiments.
Keywords
specific heat , Magnetization quantum tunneling , Molecular nanomagnets , single molecule magnets
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2008
Journal title
INORGANICA CHIMICA ACTA
Record number
1326549
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