Title of article
Dinuclear gold(III) pyrazolato complexes – Synthesis, structural characterization and transformation to their trinuclear gold(I) and gold(I/III) analogues
Author/Authors
Guang Yang، نويسنده , , José R. Mart?nez، نويسنده , , Raphael G. Raptis، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
7
From page
1546
To page
1552
Abstract
The reaction of AuCl3py with Na(pz∗) (pz∗ = pyrazolato, or substituted pyrazolato anion) yields stable dinuclear [cis -AuIIICl2(μ-pz∗)]2 complexes. In the presence of a base, the latter undergo reduction with concomitant transformation of the dinuclear View the MathML sourceAu2III-structure to trinuclear View the MathML sourceAu2IIIAuI, AuIIIView the MathML sourceAu2I (containing trans AuIIICl2-centres) and View the MathML sourceAu3I species.
Keywords
Gold complexes , X-Ray structures , Trinuclear complexes , Dinuclear complexes , Mixed-valent complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1328094
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