Title of article
Synthesis and structure of [{C7F15CO2}2AgAu(PPh3)]2 and its use in electrodeposition of gold–silver alloys
Author/Authors
Bartlett، نويسنده , , Philip N. and Cheng، نويسنده , , Fei and Cook، نويسنده , , David A. and Hector، نويسنده , , Andrew L. and Levason، نويسنده , , William and Reid، نويسنده , , Gillian and Zhang، نويسنده , , Wenjian، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
1048
To page
1051
Abstract
[{C7F15CO2}2AgAu(PPh3)]2 is obtained in good yield from the reaction of [C7F15CO2Ag] with [ClAuPPh3] in THF solution. The crystal structure shows a zig-zag Au–Ag–Ag–Au core with fluorocarboxylate ligands bridging the Au–Ag and Ag–Ag bonds and triphenylphosphine groups bound to Au. Electrodeposition from acetonitrile yields Au–Ag alloys. The deposited alloys are Ag rich and the composition varies with deposition potential.
Keywords
Gold complexes , X-ray crystal structures , Silver complexes , Electrodeposition
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328303
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