Title of article
New mononuclear Pd(II) complexes of sterically hindered bispyrazolylmethanes
Author/Authors
Jones، نويسنده , , Michael W. and Adlington، نويسنده , , Robert M. and Baldwin، نويسنده , , Jack E. and Le Pevelen، نويسنده , , Delphine D. and Smiljanic، نويسنده , , Nicolas، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
1097
To page
1101
Abstract
Three new palladium(II) complexes incorporating the bispyrazolylmethane core have been synthesised and fully characterised in the solution and solid state. Single crystal X-ray studies revealed almost complete blocking of the upper face of the palladium ion by the substituents at the 3- and 5-positions of the pyrazole rings. Preliminary screening of the complexes for palladium(II) mediated catalysis revealed good catalytic activity for the Heck coupling reaction.
Keywords
Palladium(II) complexes , Bispyrazolylmethanes , X-ray crystal structures
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328311
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