Title of article
A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]·8H2O
Author/Authors
Brylev، نويسنده , , Konstantin A. and Mironov، نويسنده , , Yuri V. and Fedorov، نويسنده , , Vladimir E. and Kim، نويسنده , , Sung-Jin and Pietzsch، نويسنده , , Hans-Jürgen and Stephan، نويسنده , , Holger and Ito، نويسنده , , Akitaka and Kitamura، نويسنده , , Noboru، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
6
From page
2686
To page
2691
Abstract
A room-temperature reaction between [Re6S8(OH)6]4− and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S8(CH3COO)6]4−. The complex was isolated as a potassium salt with the composition of K4[Re6S8(CH3COO)6]·8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV–Vis, and luminescence spectroscopies.
Keywords
Synthesis , Cluster compounds , Carboxylate Ligands , Luminescence , rhenium
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328536
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