Title of article
On the mechanisms of the reaction of dodecatungstophosphate with alkyl radicals in aqueous solutions
Author/Authors
Inna Popivker، نويسنده , , Inna and Zilbermann، نويسنده , , Israel and Maimon، نويسنده , , Eric and Matana، نويسنده , , Yosef and Cohen، نويسنده , , Haim and Meyerstein، نويسنده , , Dan، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
4202
To page
4206
Abstract
The reduced lacunary polyoxotungstate, [PW11O39]8−, reacts with the .CH2CH(OH)CH3 and .CH2C(CH3)2OH radicals via a mechanism involving β-hydroxide elimination to yield propene and 2-methyl propene respectively, and [PW11O39]7−. [PW11O39]8− is also oxidized by methyl radicals in a reaction which yields methane as the major product. It is proposed that the reactions proceed via the formation of short lived transients with W–C σ bonds.
Keywords
Polyoxotungstate , Alkyl radicals , reaction mechanisms
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328744
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