Title of article
The synthesis and structural characterization of the technetium nitrosyl complexes [TcCl(NO)(SC5H4N)(PPh3)2] and [Tc(NO)(SC5H4N)2(PPh3)]
Author/Authors
Nicholson، نويسنده , , Terrence L. and Mahmood، نويسنده , , Ashfaq and Muller، نويسنده , , Peter and Davison، نويسنده , , Alan and Storm-Blanchard، نويسنده , , Shannon and Jones، نويسنده , , Alun G.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
3
From page
484
To page
486
Abstract
The reaction of the Tc(I) complex [Tc(NO)Cl2(HOMe)(PPh3)2] with stoichiometric amounts of 2-mercatopyridine and a proton scavenger yields [Tc(NO)Cl(Spy)(PPh3)2] or [Tc(NO)(Spy)2(PPh3)], depending upon quantities of ligands employed. These two complexes have been structurally characterized. The small bite angles of the bidentate mercaptopyridine ligands cause significant deviation from octahedral coordination geometry.
Keywords
X-ray crystal structure , Bidentate , Thiolate , Technetium , nitrosyl
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329406
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