Title of article
Synthesis and reactivity of tin amide complexes
Author/Authors
Harris، نويسنده , , Lisa A.-M. and Coles، نويسنده , , Martyn P. and Fulton، نويسنده , , J. Robin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
6
From page
97
To page
102
Abstract
A terminal tin amide and a terminal tin anilide complex, (BDI)SnN(iPr2) and (BDI)SnN(H)Ar (Ar = 2,6-iPr2C6H3), respectively, have been synthesized utilizing the bulky β-diketiminate ligand, [{N(2,6-iPr2C6H3)C(Me)}2CH]−, or BDI, to stabilize the low coordinate divalent tin metal center. Only (BDI)SnN(iPr2) reacts with phenylacetylene to yield (BDI)SnCCPh, but both species react with methyl triflate to give (BDI)SnOTf and carbon dioxide, resulting in the formation of (BDI)SnOC(O)N(iPr2) and (BDI)SnOC(O)N(H)Ar.
Keywords
TIN , amide , ?-Diketiminate , Carbon dioxide
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329581
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