Title of article
Synthesis of a new tetradentate bis(imino-phosphine) ligand and its complexation with copper(I) ions
Author/Authors
Chen، نويسنده , , Chi-Shian and Yeh، نويسنده , , Wen-Yann، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
456
To page
459
Abstract
Schiff base condensation of m-phenylenediamine with two equivalents of o-(diphenylphophino)benzaldehyde products the potentially tetradentate molecule 1,3-(Ph2P(o-C6H4)CHN)2C6H4 (1) in high yield. The reaction of 1 and [Cu(NCMe)4]BF4 affords the dinuclear complex [(1,3-(Ph2P(o-C6H4)CHN)2C6H4)2Cu2](BF4)2 (2) through coordination of the imino-phosphine groups. The structure of 2 has been determined by an X-ray diffraction study.
Keywords
Dicopper(I) complex , Imino-phosphine , Tetradentate ligand
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329684
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