• Title of article

    Coordination chemistry of the heterotopic 1,2-phenylenebis(thio)diacetic acid ligand: Rhodium(I), palladium(II) and nickel(II) complexes

  • Author/Authors

    R. Berghof، نويسنده , , Christiane and Grosu، نويسنده , , Ioana Georgeta and L?nnecke، نويسنده , , Peter and G?mez-Ruiz، نويسنده , , Santiago and Silaghi-Dumitrescu، نويسنده , , Luminita and Hey-Hawkins، نويسنده , , Evamarie، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2011
  • Pages
    7
  • From page
    127
  • To page
    133
  • Abstract
    Starting from the heterotopic multidentate ligand 1,2-phenylenebis(thio)diacetic acid (1), cis-rac-[PdCl2{1,2-(HOOCCH2S)2C6H4-κ2S,S′}] (2), cis-rac-[Rh{1,2-(HOOCCH2S)2C6H4-κ2S,S′}(cod)]BF4 (3) and cis-rac-[Ni{1,2-(OOCCH2S)2C6H4-κ4O,O′S,S′}{cis-(C3H4N2)}2] (4) were prepared and characterised by X-ray diffraction and conventional spectroscopic techniques. Compounds 1–4 show extensive hydrogen-bonded networks (XH⋯O, X = O, N) in the solid state.
  • Keywords
    1 , Rhodium complex , Nickel complex , Palladium complex , X-ray crystal structure , Hydrogen bonding , 2-Phenylenebis(thio)diacetic acid
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2011
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1329889