Title of article
Structures, spectroscopy and modeling of a rare set of isomeric copper(II) complexes
Author/Authors
Comba، نويسنده , , Peter and Pandian، نويسنده , , Shanthi and Wadepohl، نويسنده , , Hubert and Wiesner، نويسنده , , Sebastian، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
7
From page
422
To page
428
Abstract
The structures and spectroscopic properties of various conformations of two diasteromeric pairs of enantiomers of pentacoordinate CuII bispidine complexes with chiral tetradentate ligands are reported. With one of the ligands an interesting type of distortional isomerism was observed experimentally, and this was studied in detail on the basis of the experimental structural and spectroscopic data (UV–Vis–NIR, EPR) and a DFT-, MM- and ligand-field-theory-based analysis.
Keywords
Density functional theory , Ligand field , Copper bispidine , Axial and rhombic , Diastereo isomer , Distortional isomerism
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329923
Link To Document