Title of article
Thioamide, urea and thiourea bridged rhenium(I) complexes as luminescent anion receptors
Author/Authors
Maurice O. Odago، نويسنده , , Maurice O. and Hoffman، نويسنده , , Amanda E. and Carpenter، نويسنده , , Russell L. and Tse، نويسنده , , Douglas Chi Tak and Sun، نويسنده , , Shih-Sheng and Lees، نويسنده , , Alistair J.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
8
From page
558
To page
565
Abstract
Thioamides, urea and thiourea derivatives of 2,6-pyridinedicarbonyl dichloride, isophthaloyl dichloride and terephthaloyl dichloride have been synthesized. These ligands have been incorporated in dinuclear rhenium(I) diimine tricarbonyl complexes and the anion recognition properties of these complexes have been studied by luminescence, UV–Vis and 1H NMR spectroscopic methods. The complexes act as receptors for anions via hydrogen bonding and electrostatic interactions. The anion sensing properties of the complexes are compared to earlier amide-based dinuclear rhenium(I) tricarbonyl complexes.
Keywords
Bridged rhenium carbonyl complexes , Anion recognition , Supramolecular chemistry , Luminescence , Thioamide and amidothiourea , Urea and thiourea
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329940
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