Title of article
1D chain coordination assembly of [Mn4(hmp)6(NO3)2]2+ single-molecule magnets linked by the photochromic [FeNO(CN)5]2− precursor
Author/Authors
Kushch، نويسنده , , Lyudmila A. and Sasnovskaya، نويسنده , , Valentina D. and Yagubskii، نويسنده , , Eduard B. and Khasanov، نويسنده , , Salavat S. and Simonov، نويسنده , , Sergey V. and Shibaeva، نويسنده , , Rimma P. and Korolev، نويسنده , , Alexander V. and Starichenko، نويسنده , , Denis V. and Anokhin، نويسنده , , Anatoly O. and Irkhin، نويسنده , , Valentin Yu. and Shva، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
5
From page
169
To page
173
Abstract
The first heterometallic chain cluster {[Mn4(hmp)6(NO3)2FeNO(CN)5·4CH3CN}n (1) based on the [Mn4(hmp)6] SMM has been synthesized. 1 has one-dimensional chain structure: the [Mn4(hmp)6] units are linked via CN-groups of nitroprusside anions. Its magnetic and relaxation properties and low temperature IR spectra under light irradiation have been investigated. The ferromagnetic exchange constants have been calculated.
Keywords
Single-chain magnets (SCMs) , One-dimensional chain , Jahn–Teller elongation , magnetic susceptibility , Single-molecule magnets (SMMs) , Photochromic FeNO(CN)5 anion
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1330134
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