Title of article
The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine
Author/Authors
Nilsson، نويسنده , , Jessica and Colbran، نويسنده , , Stephen B. and Behrens، نويسنده , , Ulrich and Rehder، نويسنده , , Dieter and Nordlander، نويسنده , , Ebbe، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
490
To page
493
Abstract
Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)3, with VIVOSO4·5H2O resulted in an unexpected redox reaction producing [VIIILH][VIIILH2][PF6]3·1.5H2O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate VIII by reduction of VV from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions.
Keywords
vanadium , Vanadyl cation , Reduction , Ascidians
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2012
Journal title
INORGANICA CHIMICA ACTA
Record number
1331307
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