Crystal structure and magnetic properties of novel Hf3Ni2Si3-type R3Co2Ge3 compounds (R=Y, Sm, Tb–Tm)

The novel R 3Co2Ge3 compounds with R =Y, Sm, Tb–Tm adopt the Hf3Ni2Si3-type structure (ordered variant of the Ca3Ga5-type one, space group Cmcm ). Sm3Co2Ge3, Tb3Co2Ge3, Ho3Co2Ge3 and Er3Co2Ge3 undergo an antiferromagnetic-type ordering and Tb3Co2Ge3 demonstrates a field-sensitive magnetic behavior. Tm3Co2Ge3 is a pure paramagnet down to 5 K, whereas Y3Co2Ge3 demonstrates Pauli paramagnetism down to ∼120 K. In zero applied field and between ∼50 and ∼15 K Tb3Co2Ge3 shows a non-collinear antiferromagnetic ordering with wave vectors K 0=[0, 0, 0] and K 1=[±1/3, 0, 0] and a magnetic unit cell 3aTb3Co2Ge2×bTb3Co2Ge3×cTb3Co2Ge33aTb3Co2Ge2×bTb3Co2Ge3×cTb3Co2Ge3 , whereas below ∼15 K it exhibits a complex antiferromagnetic ordering with K 0=[0, 0, 0], K 1=[±1/3, 0, 0] and K 2=[1/2, 0, 0] wave vectors and magnetic unit cell 6aTb3Co2Ge2×bTb3Co2Ge2×cTb3Co2Ge2