Title of article
Synthesis and reactions of B-vinylcarboranes
Author/Authors
Kuanysh Z. Kabytaev، نويسنده , , Alexander V. Safronov، نويسنده , , Satish S. Jalisatgi، نويسنده , , M. Frederick Hawthorne، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
3
From page
106
To page
108
Abstract
B-Vinylcarboranes were prepared via the palladium-catalyzed cross-coupling of iodocarboranes with vinylmagnesium bromide. Further transformations of the 9-vinyl-1,2-dicarba-closo-dodecaborane side chain yielded bromination, epoxidation, dihydroxylation, oxidative cleavage, radical sulfur addition, and hydroboration/oxidation products.
Keywords
Electrophilic addition , radical reaction , Cross-coupling , Carboranes , Oxidation
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1369607
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