• Title of article

    Synthesis, structure and redox behaviour of gold and silver complexes with 3-ferrocenylpyridine

  • Author/Authors

    Eva M. Barranco، نويسنده , , Olga Crespo، نويسنده , , M.Concepci?n Gimeno، نويسنده , , Peter G Jones، نويسنده , , Antonio Laguna، نويسنده , , M.Dolores Villacampa، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 1999
  • Pages
    7
  • From page
    258
  • To page
    264
  • Abstract
    3-Ferrocenylpyridine (Fcpy) reacts with gold(I) derivatives to afford neutral, [AuR(Fcpy)] (R=Cl, C6F5), or cationic complexes, [Au(Fcpy)(PPh3)]OTf. Reaction with [Au(C6F5)2(OEt2)2]ClO4 or [Au(C6F5)3(OEt2)] gives the gold(III) complexes [Au(C6F5)2(Fcpy)2]ClO4 or [Au(C6F5)3(Fcpy)], respectively. The silver derivatives [Ag(Fcpy)(PPh3)]OTf and [Ag(OTf)(Fcpy)2] have also been synthesised.
  • Keywords
    Ferrocenylpyridine , Redox behaviour , Gold , Silver , Ferrocene
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    1999
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1369676