Title of article
Reaction of nickelocene with 1,3-dimesitylimidazolium chloride
Author/Authors
Colin D Abernethy، نويسنده , , Alan H، نويسنده , , Cowley، نويسنده , , Richard A Jones، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
3
From page
3
To page
5
Abstract
Treatment of nickelocene with 1,3-dimesitylimidazolium chloride affords the corresponding carbene complex, (η5-C5H5)NiCl(carbene) (5). The structure of 5 was determined by X-ray crystallography. The distorted trigonal planar nickel atom is attached to an η5-Cp, a carbene, and a chloride ligand. Compound 5 reacts with MeLi to afford (η5-C5H5)Ni(Me)(carbene).
Keywords
nickel , Imidazolium , Cyclopentadienyl , carbene complex , Chlorine
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1369788
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