• Title of article

    Photoluminescent macrocyclic Pd(II) and Pt(II) dimeric complexes with Ph2P–CC–PPh2 spacer

  • Author/Authors

    Dengfeng Xu، نويسنده , , Hunter J Murfee، نويسنده , , Wytze E. van der Veer، نويسنده , , Bo Hong، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    11
  • From page
    53
  • To page
    63
  • Abstract
    The synthesis and characterization of macrocyclic Pd(II)/Pt(II) dimers and their monomeric precursors with diphosphine spacer Ph2P–CC–PPh2 (C2P2) are reported. Their excited-state properties, including solvent-dependent absorption, emission and quantum yield, are studied. When the solvent polarity increases, solvatochromic absorption band shifts to higher energy, emission maximum shifts to lower energy, and quantum yield decreases. In addition, the host–guest behavior of these new inorganic macrocycles is also reported here.
  • Keywords
    Inorganic macrocycles , Polyphosphines , host–guest , Pd(II) and Pt(II) complexes , Photoluminescence
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1369796