Title of article
Photoluminescent macrocyclic Pd(II) and Pt(II) dimeric complexes with Ph2P–CC–PPh2 spacer
Author/Authors
Dengfeng Xu، نويسنده , , Hunter J Murfee، نويسنده , , Wytze E. van der Veer، نويسنده , , Bo Hong، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
11
From page
53
To page
63
Abstract
The synthesis and characterization of macrocyclic Pd(II)/Pt(II) dimers and their monomeric precursors with diphosphine spacer Ph2P–CC–PPh2 (C2P2) are reported. Their excited-state properties, including solvent-dependent absorption, emission and quantum yield, are studied. When the solvent polarity increases, solvatochromic absorption band shifts to higher energy, emission maximum shifts to lower energy, and quantum yield decreases. In addition, the host–guest behavior of these new inorganic macrocycles is also reported here.
Keywords
Inorganic macrocycles , Polyphosphines , host–guest , Pd(II) and Pt(II) complexes , Photoluminescence
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1369796
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