Title of article
Structural and electronic properties of (2,2-trans)-dirhodium(II) tetrakis(N-phenylacetamidate)
Author/Authors
Cassandra T Eagle، نويسنده , , David G Farrar، نويسنده , , Grant N Holder، نويسنده , , William T. Pennington، نويسنده , , Rosa D Bailey، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
5
From page
90
To page
94
Abstract
We have synthesized and characterized the first known 2,2-trans isomer of the N-substituted dirhodium(II) tetrakisacetamidate, Rh2(RNAc)4, class of compounds. The bis benzonitrile adduct exhibits a unique orthogonal arrangement of the axial aromatic rings in the solid state. Structural and electronic features suggest the presence of π-backbonding.
Keywords
Aromatic rings , rhodium acetate , ?-Backbonding
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1369801
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