Title of article
Functionalized styryl iridium(III) complexes as active second-order NLO chromophores and building blocks for SHG polymeric films
Author/Authors
Claudia Dragonetti، نويسنده , , Alessia Colombo، نويسنده , , Daniele Marinotto، نويسنده , , Stefania Righetto، نويسنده , , Dominique Roberto، نويسنده , , Adriana Valore، نويسنده , , Muriel Escadeillas، نويسنده , , Véronique Guerchais، نويسنده , , Hubert Le Bozec، نويسنده , , Abdou Boucekkine، نويسنده , , Camille Latouche، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
5
From page
568
To page
572
Abstract
We studied the second-order NLO properties in solution of various Ir(III) acetylacetonate complexes bearing a substituted cyclometallated 4-styryl-2-phenylpyridine (ppy-4-styryl-R, with R = NEt2, OMe, H, NO2) with the EFISH technique. The dipole moments were evaluated by Density Functional Theory (DFT) calculations.
We have also investigated the Second Harmonic Generation (SHG) of composite films based on the various cyclometallated Ir(III) complexes dispersed and oriented in a polymethylmethacrylate (PMMA) matrix.
Keywords
Cyclometallated iridium(III) complexes , Second-order nonlinear optics , Second harmonic generation , EFISH
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1369889
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