Title of article
A new heterobimetallic palladium–[60]fullerene complex with bidentate bis-1,1′-[P]2-ferrocene ligand
Author/Authors
Vasily V Bashilov، نويسنده , , Tatiana V Magdesieva، نويسنده , , Dmitry N Kravchuk، نويسنده , , Pavel V. Petrovskii، نويسنده , , Allan G Ginzburg، نويسنده , , Kim P Butin، نويسنده , , Viatcheslav I. Sokolov، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
5
From page
37
To page
41
Abstract
A new heterobimetallic palladium–[60]fullerene complex with ferrocene bis-phosphine ligand was prepared using alternative paths: either via addition reaction of Pd2(dba)3·C6H6 (dba=dibenzylidenacetone) in the presence of 1,1′-bis(diphenylphosphino)ferrocene (dppf) to C60, or via electrochemical activation of C60 to generate C602− anions, which then react with PdCl2 and dppf to yield the target complex. The obtained (η2-C60)Pd(dppf) complex was characterized by 1H- and 31P-{1H}-NMR and electronic spectroscopy as well as electrochemically.
Keywords
Ferrocene diphosphine ligand , Palladium , Heterobimetallic complex , Synthesis , Molecular orbitals , Fullerene , Electrochemistry
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1370022
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