• Title of article

    Synthesis of 1,4-benzodiazepinones via palladium-catalysed allene carbopalladation/amination domino sequence

  • Author/Authors

    Micol Rigamonti، نويسنده , , Guillaume Prestat، نويسنده , , Gianluigi Broggini، نويسنده , , Giovanni Poli، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2014
  • Pages
    7
  • From page
    149
  • To page
    155
  • Abstract
    Vinyl-substituted 1,4-benzodiazepinones were obtained in good yields (10 examples, 61–82% yield) via the reaction between N-allenyl anthranyl amides and aryl iodides under Pd(0) catalysis. This new single cycle catalytic domino transformation involves a C–C followed by an N–C bond formation.
  • Keywords
    Carbopalladation , Amination , 1 , Palladium , domino reactions , 4-Benzodiazepinones , Allene
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2014
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370443