Title of article
Unprecedented formation of ruthenium 2-mercaptobenzothiazole complex
Author/Authors
Wen-Lin Huang، نويسنده , , Guan-Jie Hung، نويسنده , , Yih-Hsing Lo، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
5
From page
120
To page
124
Abstract
The CS2 insertion of ruthenium chloride complex Tp(Ph2Cdouble bond; length as m-dashNH)(PPh3)Ru–Cl (1) in the presence of CH3OH resulted in the O-methyldithiocarbonate complex Tp(PPh3)Ru (κ2-S2COCH3) (3). Attractively, the analogous reaction with CS2 in the presence of PhN3 in toluene at reflux led to unprecedented formation of the ruthenium 2-mercaptobenzothiazole complex Tp(PPh3)Ru(κ2-S,N–Ndouble bond; length as m-dashCS2C6H4) (4), possibly via the C–H activation of an imido intermediate. Theoretical calculations support the proposed mechanism.
Keywords
TP , Carbon disulfide , O-methyldithiocarbonate , 2-Mercaptobenzothiazole , Ruthenium
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1370640
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