Title of article
Rhodium-catalyzed reduction of α-amino acid precursors using chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligands
Author/Authors
Fabien Robert، نويسنده , , Denis Sinou، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
4
From page
99
To page
102
Abstract
The enantioselectivity of the hydrogenation of some unsaturated amino acids using rhodium complexes in association with chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligands is higher (ee values of up to 60%) in water as the solvent in the presence of SDS than in methanol.
Keywords
Surfactant , asymmetric hydrogenation , Rhodium , Chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligand
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1370817
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