• Title of article

    The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands

  • Author/Authors

    Valentine P Ananikov، نويسنده , , Sergey A. Mitchenko، نويسنده , , Irina P. Beletskaya، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    6
  • From page
    290
  • To page
    295
  • Abstract
    An unusual fact of CC reductive elimination reaction in bis-chelated Pt(IV) complexes under mild conditions was studied. It has been shown that breaking at least one of the chelate rings is required to promote a carboncarbon bond formation reaction. An intermediate complex, which resulted from a chelate ligand breaking process, was detected directly in the reaction mixture using 2D 1H–195Pt heteronuclear NMR spectroscopy.
  • Keywords
    Pt(IV) , 2D-NMR , 195Pt-NMR , C?C reductive elimination , Catalytic reaction
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370844

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1370844