• Title of article

    Trends in back-bonding in the series trans-[M(CCR)Cl(PH3)4] (M=Fe, Ru, Os; R=H, Ph, C6H4NO2-4)

  • Author/Authors

    Christopher D. Delfs، نويسنده , , Rob Stranger، نويسنده , , Mark G. Humphrey، نويسنده , , Andrew M. McDonagh، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    208
  • To page
    212
  • Abstract
    The electronic structure of the complexes trans-[M(CCR)Cl(PH3)4] (M=Fe, Ru, Os; R=H, Ph, C6H4NO2-4) has been investigated using approximate density functional theory in order to examine the MC back-bonding interaction. For all three metal systems, the π back-bonding increases in the order R=H
  • Keywords
    Metal–carbon backbonding , Density functional theory , Relativistic effects
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370942

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1370942