Title of article
New silyl-substituted phosphaalkenes Mes*Pdouble bond; length as m-dashC(Cl)–Si(Cl)PhR, promising building blocks in silicon and phosphorus chemistry
Author/Authors
Agota Bartok، نويسنده , , Raluca Septelean، نويسنده , , Petronela M. Petrar، نويسنده , , Gabriela Nemes، نويسنده , , Luminita Silaghi-Dumitrescu، نويسنده , , Henri Ranaivonjatovo، نويسنده , , Sonia Mallet-Ladeira، نويسنده , , Nathalie Saffon، نويسنده , , Catherine Hemmert، نويسنده , , Heinz Gornitzka، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2013
Pages
6
From page
200
To page
205
Abstract
Three new silyl-substituted phosphaalkenes Mes*Pdouble bond; length as m-dashC(Cl)–Si(Cl)PhR (R = chlorine, 1; R = 9-methylfluoren-9-yl, 2; R = 9-trimethylsilylfluoren-9-yl, 3) were obtained and completely characterized. The coordination compounds 4 and 5, resulting from the reaction between Au(SMe2)Cl and 1 and 3, respectively, are also described. All these compounds are potential precursors of phosphasilaallenes, not stabilized until now and new ligands in transition metal chemistry.
Keywords
Gold complexes , Phosphasilapropenes , Low coordinate phosphorus compounds , Multiple bonding
Journal title
Journal of Organometallic Chemistry
Serial Year
2013
Journal title
Journal of Organometallic Chemistry
Record number
1371309
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