Title of article
Ruthenium–porphyrin-catalyzed carbenoid addition to allylic compounds: application to [2,3]-sigmatropic rearrangements of ylides
Author/Authors
Gérard Simonneaux، نويسنده , , Erwan Galardon، نويسنده , , Christine Paul-Roth، نويسنده , , Mihaela Gulea، نويسنده , , Serge Masson، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
4
From page
360
To page
363
Abstract
The catalytic effectiveness of ruthenium porphyrins for ylide generation in reactions of ethyl diazoacetate and diisopropyl diazomethylphosphonate with allylic amines, sulfides and iodides is described for the first time. These reactions result mainly in products of the [2,3]-sigmatropic rearrangement of intermediate allylic ylides.
Keywords
Porphyrins , Ruthenium , Sigmatropic , Catalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1371616
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