Title of article
Catalytic activity of gold nanoclusters in intramolecular hydroamination of alkenes and alkynes with toluenesulfonamide under aerobic and basic conditions
Author/Authors
Hiroaki Kitahara، نويسنده , , Hidehiro Sakurai، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
8
From page
442
To page
449
Abstract
Gold nanoclusters stabilized by a hydrophilic polymer, poly(N-vinyl-2-pyrrolidone) (Au:PVP), catalyzed the intramolecular hydroamination of toluenesulfonamides to unactivated alkenes/alkynes in EtOH under aerobic and basic conditions. The reaction proceeds via anti-addition of toluenesulfonamide to the alkenes assisted by π-activation of the gold clusters.
Keywords
Gold nanocluster , Aerobic conditions , Intramolecular hydroamination
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373546
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