Title of article
Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compounds
Author/Authors
Masato Ueda، نويسنده , , Atsushi Saitoh، نويسنده , , Norio Miyaura، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
3
From page
145
To page
147
Abstract
The hydrogenation of ethanediol 1-phenylethenylboronic ester was carried out at −20 °C under a hydrogen atmosphere (9 atm) in the presence of [Rh(cod)2]BF4–(R)-BINAP (3 mol%). After alkaline hydrogen peroxide oxidation, the reaction gave 1-phenylethanol with 80% e.e.
Keywords
Hydrogenation , Asymmetric synthesis , boron and compounds
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1373725
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