• Title of article

    Palladium π-adduct of corannulene

  • Author/Authors

    Sarah N. Spisak، نويسنده , , Alexander S. Filatov، نويسنده , , Marina A. Petrukhina، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2011
  • Pages
    4
  • From page
    1228
  • To page
    1231
  • Abstract
    The ternary palladium π-adduct of corannulene and benzene, [Pd6Cl12·(C20H10)2·(C6H6)2]·C6H6 (1), has been prepared by reacting the cubic Pd6Cl12-cluster with C20H10 in benzene. It was structurally characterized to reveal η1-binding of Pd6Cl12 to a hub C-atom of the convex surface of corannulene (Pd⋯C, 3.085(3) Å) and its η6-complexation to benzene (Pd⋯Ccentroid, 3.431(3) Å). The behavior and persistence of 1 in some aromatic solvents has been revealed by UV–vis and 1H NMR spectroscopy studies.
  • Keywords
    Palladium cluster , buckybowls , corannulene , Non-planar aromatic systems
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2011
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1373736

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1373736