Title of article
1-Diisopropylaminophospholes: synthesis and X-ray characterisations of new palladium and platinum complexes
Author/Authors
Jérôme Hydrio، نويسنده , , Maryse Gouygou، نويسنده , , Fréderic Dallemer، نويسنده , , Gilbert G.A Balavoine، نويسنده , , Jean-Claude Daran، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
8
From page
19
To page
26
Abstract
Starting from palladium precursor [Pd(CH3CN)2Cl2], 1-diisopropylaminophospholes give dinuclear complexes, [Pd(phosphole)Cl2]2, which proved to be intermediates in the formation of mononuclear complexes, cis-[Pd(phosphole)2Cl2]. In contrast with the platinum precursor, only mononuclear complexes, [Pt(phosphole)2Cl2], are obtained with both cis and trans configurations. These new complexes were fully characterised by X-ray crystallography.
Keywords
phosphole , 1-Diisopropylaminophosphole , Complexes , Palladium , Platinum
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1373787
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