Title of article
The Cl2(PCy3)(IMes)Ru(CHPh) catalyst: olefin metathesis versus olefin isomerization
Author/Authors
Damien Bourgeois، نويسنده , , Ange Pancrazi، نويسنده , , Steven P. Nolan، نويسنده , , Joëlle Prunet، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
6
From page
247
To page
252
Abstract
While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction.
Keywords
Ruthenium , Metathesis , Carbene , Isomerization
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1373847
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