Title of article
P(MeNMCH2CH2)3N: an effective catalyst for trimethylsilycyanation of aldehydes and ketones
Author/Authors
Zhigang Wang، نويسنده , , Brandon Fetterly، نويسنده , , John G. Verkade، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
6
From page
161
To page
166
Abstract
The title non-ionic phosphazane base promotes the trimethylsilycyanation of aryl and alkyl aldehydes and ketones in moderate to high yields at room temperature. 29Si-NMR spectral evidence for the intermediacy of a phosphazane phosphorus–silicon adduct is presented.
Keywords
Transannulation , Bicyclic phosphazane , Aldehyde trimethysilylcyanation , Hypercoordinate silicon , Ketone trimethylsilylcyanation , Aminophosphine catalyst
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374044
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