• Title of article

    Novel 2-indenyl ansa-zirconocenes for the polymerization of α-olefins

  • Author/Authors

    Matthew N Herzog، نويسنده , , James C.W. Chien، نويسنده , , Marvin D Rausch، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    7
  • From page
    29
  • To page
    35
  • Abstract
    A new synthetic route to C-2 bridged indenyl metallocenes utilizing the anion of 1-indanone has been developed. Two new ansa-zirconocene complexes 1a and 1b were synthesized and examined as precursors for the polymerization of α-olefins. These metallocenes were shown to be active for the polymerization of ethylene and for the oligiomerization of propylene when activated with excess methylaluminoxane (MAO).
  • Keywords
    2-Indenyl , Metallocene , Zirconium , Olefin polymerization
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374451