Title of article
Investigation of titanium-catalysed dehydrogenative coupling and hydrosilylation of phenylhydrogenosilanes in a one-pot process
Author/Authors
Julien Garcia، نويسنده , , Daniel J.M. Meyer، نويسنده , , Denis Guillaneux، نويسنده , , Joël J.E. Moreau، نويسنده , , Michel Wong Chi Man، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
7
From page
2427
To page
2433
Abstract
Titanium-catalysed dehydrocondensation and hydrosilylation of primary, secondary and tertiary phenylsilanes have been investigated in a one-pot process with Cp2Ti(OPh)2 as catalyst by NMR studies. Only primary and secondary silanes were found to undergo simultaneous dehydrogenative coupling and hydrosilylation reactions to produce the functional polysilanes.
Keywords
Polysilane , Dehydrogenative coupling , Hydrosilylation , titanium catalyst , Polymerisation , NMR studies
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374534
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